Bookmarks can be created in any order and later moved up/down and promoted/demoted in the bookmark hierarchy, using the dedicated icons above the Bookmarks panel in your PDF viewer:
To move a bookmark up or down in the bookmarks panel
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Select a document in the Source Documents tab.
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Click the Document Mark Up tab. The document will open in the Document Mark Up tab.
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Click the Bookmarks tab to the left of the document. The Bookmarks pane opens.
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Select a bookmark and click
to move the bookmark up in the list of bookmarks or
to move it down.
To demote or promote a bookmark
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Select a document in the Source Documents tab.
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Click the Document Mark Up tab. The document will open in the Document Mark Up tab.
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Click the Bookmarks tab to the left of the document. The Bookmarks pane opens.
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Select a primary heading bookmark and click
to demote it to a sub-heading or select a sub-heading and click
to promote it to a primary heading.